By Archer K.J., Dumur C.I., Joel S.E.
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Extra info for Assessing quality of hybridized RNA in Affymetrix GeneChip experiments using mixed-effects models
First, though, let us look at previous techniques used to measure dipole moments of this type. 1 Previous Experimental Techniques to Measure Transition Dipole Moments In the past, physicists have made use of various methods to determine the transition dipole moments between quantum levels in atoms and molecules, branching ratios of transitions from a single upper level to various lower levels, and the lifetimes of excited levels. 109'110 Branching ratios and relative transition dipole moments can be inferred from the relative intensities of fluorescence lines.
Reproduced from . 8: Schematic diagram of the photodissociation process. Figure (a) shows excitation to a repulsive state. Figure (b) shows excitation to a bound state above the dissociation limit. Both cases result in the breakup of the molecule into its atomic constituents. 22 v-(AE/m) . In this work, we use the process of molecular photolysis to create a population of excited atoms with well-defined and controllable velocities. Such populations are then used to study the velocity dependence of the cesium 5Dj +6Pr ->7Dr+6SV2 energy pooling collision process (see chapters 3-5).
11 Note the difference in the x-axis scale for the different measurements. 34 2 . 0 J> o Q. 125 (dotted line). 2A. Reproduced from . 35 has pointed out, the accuracy of measured lifetimes increases with the number of vibrational level pairs between the upper and lower states that are studied. m also measured the relative intensities of the transitions from selected upper levels to all ground state levels. By fitting these intensities as described above in this section, the authors were able to determine the relative transition dipole moment function between the D^TL and XlH+ electronic states.
Assessing quality of hybridized RNA in Affymetrix GeneChip experiments using mixed-effects models by Archer K.J., Dumur C.I., Joel S.E.